Enantiomerically pure [3.3.0] fused lactones of ribofuranosyl sugars and nucleosides at positions 2,3 of the ribofuranose ring have been prepared by intramolecular addition of radicals onto the α-position of α,β-unsaturated esters.
S. Velázquez, S. Huss and M. Camarasa, J. Chem. Soc., Chem. Commun., 1991, 1263 DOI: 10.1039/C39910001263
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