Issue 16, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Ditopic crown thioethers. Synthesis and structures of anti-[Cu2(L1)(PPh2Me)2][ClO4]2 and syn-[Cu2(L1)(µ-PPh2CH2CH2PPh2)][PF6]2, (L1= 2,5,8,17,20,23-hexathia[9](1,2)[9](6,5)cyclophane)

Stephen J. Loeb  and  George K. H. Shimizu  

Abstract

The ditopic crown thioether, 2,5,8,17,20,23-hexathia[9](1,2)[9](6,5)cyclophane contains two S3 coordination sites separated by an o-xylyl spacing unit which allows coordination of two metal ions in either an anti or syn arrangement as demonstrated by the structures of anti-[Cu2(L1)PPh2Me)2][ClO4]2 and syn-[Cu2(L1)(µ-PPh2CH2CH2PPh2)][PF6]2.

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Article information

DOI
https://doi.org/10.1039/C39910001119
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1119-1121

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Ditopic crown thioethers. Synthesis and structures of anti-[Cu2(L1)(PPh2Me)2][ClO4]2 and syn-[Cu2(L1)(µ-PPh2CH2CH2PPh2)][PF6]2, (L1= 2,5,8,17,20,23-hexathia[9](1,2)[9](6,5)cyclophane)

S. J. Loeb and G. K. H. Shimizu, J. Chem. Soc., Chem. Commun., 1991, 1119 DOI: 10.1039/C39910001119

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