In the presence of ozone and an appropriate catalyst, nitrogen dioxide acts as a powerful nitrating agent at low temperatures, converting arenes into polynitro derivatives in good yields.
H. Suzuki, T. Murashima, K. Shimizu and K. Tsukamoto, J. Chem. Soc., Chem. Commun., 1991, 1049 DOI: 10.1039/C39910001049
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