The (–)-8-phenylmenthol ester of N-Boc-glycine is brominated with N-bromosuccinimide and the bromo-compound is reduced with tri-n-butyldeuteriostannane to give the chiral glycine derivative in high optical yield which upon hydrolysis yields the amino acid without racemisation.
D. P. G. Hamon, P. Razzino and R. A. Massy-Westropp, J. Chem. Soc., Chem. Commun., 1991, 332 DOI: 10.1039/C39910000332
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