The optically active amine-boryl radical IpcḂH â†� NMe2CH2CH2NMe2→ BH2Ipc (Ipc = isophinocampheyl)abstracts hydrogen enantioselectively from the α-C–H group of methyl 2-phenylpropanoate; partial kinetic resolution of the ester has been achieved in a catalytic manner.
P. L. H. Mok and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1991, 150 DOI: 10.1039/C39910000150
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