Issue 7, 1990

One-pot annulation to tricyclo[5.3.1.03,8]undecane-2,6-diones by sequential three-fold Michael reactions. A formal synthesis of (±)-seychellene

Abstract

Lewis acid-assisted triple Michael reactions yield tricyclo[5.3.1.03,8]undecane-2,6-dione derivatives from the trimethylsilyl enol ethers of cyclohex-2-enones and divinyl ketone. The application of this reaction allowed a formal synthesis of (±)-seychellene.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 2109-2113

One-pot annulation to tricyclo[5.3.1.03,8]undecane-2,6-diones by sequential three-fold Michael reactions. A formal synthesis of (±)-seychellene

H. Hagiwara, A. Okano and H. Uda, J. Chem. Soc., Perkin Trans. 1, 1990, 2109 DOI: 10.1039/P19900002109

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