Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or-stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.
K. Mikami, K. Kawamoto, T. Loh and T. Nakai, J. Chem. Soc., Chem. Commun., 1990, 1161 DOI: 10.1039/C39900001161
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