Electroreduction of dichlorosilanes, such as 1,1-dichlorodialkylsilanes, 1,2-dichlorotetra-alkyldisilanes, and 1,4-bis(chlorodialkylsilyl)benzenes, with Mg electrodes in a single-compartment cell was found to yield the corresponding polysilanes.
T. Shono, S. Kashimura, M. Ishifune and R. Nishida, J. Chem. Soc., Chem. Commun., 1990, 1160 DOI: 10.1039/C39900001160
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