Nucleophiles add to C-1 of (vinylketene)tricarbonyliron(0) complexes to give β,γ-unsaturated carbonyl derivatives, whereas nucleophilic attack on a (vinylketenimine)tricarbonyliron(0) analogue occurs at C-2 and leads, after an oxidative work-up, to β,γ-unsaturated amides containing an a quaternary centre.
L. Hill, C. J. Richards and S. E. Thomas, J. Chem. Soc., Chem. Commun., 1990, 1085 DOI: 10.1039/C39900001085
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