Shape-selective oxidation of alkanes with H2O2 is catalysed by pentasil zeolite titanosilicate; the rates for oxidation of linear alkanes are much higher than those of branched and cyclic alkanes.
T. Tatsumi, M. Nakamura, S. Negishi and H. Tominaga, J. Chem. Soc., Chem. Commun., 1990, 476 DOI: 10.1039/C39900000476
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