Issue 5, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolated free-radical pairs in Rb+ 18-crown-6 TCNQ– single crystals (TCNQ = tetracyanoquinodimethane)

Martin C. Grossel,   Francis A. Evans,   Joseph A. Hriljac,   John R. Morton,   Y. Lepage,   Keith F. Preston,   Leslie H. Sutcliffe  and  Anthony J. Williams  

Abstract

An X-ray crystallographic study of Rb+ 18-crown-6 TCNQ– reveals the presence of localised pairs of radical anions rather than the stacks commonly encountered in salts of TCNQ–; the spin–spin tensor of the excited triplet observed and measured by EPR spectroscopy of a single crystal has principal values and directions appropriate for the location of the intrinsic pair within the crystal structure.

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Article information

DOI
https://doi.org/10.1039/C39900000439
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 439-441

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Isolated free-radical pairs in Rb+ 18-crown-6 TCNQ– single crystals (TCNQ = tetracyanoquinodimethane)

M. C. Grossel, F. A. Evans, J. A. Hriljac, J. R. Morton, Y. Lepage, K. F. Preston, L. H. Sutcliffe and A. J. Williams, J. Chem. Soc., Chem. Commun., 1990, 439 DOI: 10.1039/C39900000439

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