Intrazeolite attachment of a Ge–Mo heterobimetallic complex
Abstract
HY zeolite encapsulated Cl2(thf)GeMo(CO)5(thf = tetrahydrofuran), studied by EXAFS, in situ Fourier transform spectroscopy, and temperature programmed desorption (TPD) MS, attaches to the zeolite pore system through the Ge-moiety with retention of the Ge–Mo bond, whereas a large fraction of the intrazeolite –Mo(CO)5 moieties remain unaffected by the anchoring reaction.