Reduction of the alkenic bond of testosterone and androst-4-ene-3,17-dione by the 5α-reductase enzyme of Penicillium decumbens proceeds with trans stereochemistry.
H. L. Holland, W. Xu and D. W. Hughes, J. Chem. Soc., Chem. Commun., 1989, 1760 DOI: 10.1039/C39890001760
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