Issue 17, 1989

Biosynthesis of solanapyrone A, a phytotoxin of Alternaria solani

Abstract

The building blocks and the origin of hydrogen and oxygen atoms in solanapyrone A (1) were determined by incorporation experiments employing sodium [1-13C]-, [1,2-13C2]-, [1-13C, 18O2]-, [1-13C, 2H3]-, [2-13C, 2H3]acetates and [S-13CH3] methionine; the labelling pattern supports the hypothesis that (1) is biosynthesized via the intramolecular Diels–Alder reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1282-1284

Biosynthesis of solanapyrone A, a phytotoxin of Alternaria solani

H. Oikawa, T. Yokota, T. Abe, A. Ichihara, S. Sakamura, Y. Yoshizawa and J. C. Vederas, J. Chem. Soc., Chem. Commun., 1989, 1282 DOI: 10.1039/C39890001282

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