Synthesis of hydroxo-organo-complexes of the nickel group elements
Abstract
The considerable nucleophilicity of the OH bridges in the new hydroxo complexes [(C6F5)2M(µ-OH)2M(C6F5)2]2–(M = Ni, Pd, Pt) is indicated by high field proton resonances and the formation of µ-pyrazolate derivatives from [(C6F5)Ni(µ-OH)2Ni(C6F5)2]2–.