Issue 12, 1989

Nucleophilic displacement of methide from silicon. Steric compression of geminal trimethylsilyl groups?

Abstract

6,6-Bis(trimethylsilyl)norbornan-endo-2-ol (6) undergoes base-induced intramolecular displacement of a Si–Me group with formation of (9), in contrast to the monosilylated analogue (7).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 774-775

Nucleophilic displacement of methide from silicon. Steric compression of geminal trimethylsilyl groups?

W. Kirmse and F. Söllenböhmer, J. Chem. Soc., Chem. Commun., 1989, 774 DOI: 10.1039/C39890000774

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