Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl2(PPhCPhcph)(PEt3)] and cis-[PtI(PPhMeCPhCPh)(PPh3)]

Salih S. Al-Juaid; Duncan Carmichael; Peter B. Hitchcock; Siegfried Lochschmidt; Angela Marinetti; François Mathey; John F. Nixon

doi:10.1039/C39880001156

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Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]

Salih S. Al-Juaid, Duncan Carmichael, Peter B. Hitchcock, Siegfried Lochschmidt, Angela Marinetti, François Mathey and John F. Nixon

Abstract

1,2,3-Triphenylphosphirene undergoes only η¹-co-ordination with Pt^II complexes whereas with Pt⁰ centres insertion also occurs to yield phosphaplatinacyclobutene products.

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DOI: https://doi.org/10.1039/C39880001156
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1988, 1156-1158

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Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]

S. S. Al-Juaid, D. Carmichael, P. B. Hitchcock, S. Lochschmidt, A. Marinetti, F. Mathey and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1988, 1156 DOI: 10.1039/C39880001156

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Journal of the Chemical Society, Chemical Communications

Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]

Abstract

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Download Citation

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Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]

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