Issue 11, 1988
From the journal:

Journal of the Chemical Society, Dalton Transactions

The syntheses and electrochemistry of some molybdenum mononitrosyl complexes containing the tripodal ligand [Co(η5-C5H5){P([double bond, length half m-dash]O)(OEt)2}3]–

Sithy S. Salam,   Christopher J. Jones  and  Jon A. McCleverty  

Abstract

The bimetallic complex [Mo(NO)(CO)2L](L =[Co(η5-C5H5){P([double bond, length half m-dash]O)(OEt)2}3]–) may be oxidatively halogenated using iodine to give [Mo(NO)Ll2] which is a monomeric complex containing a 16-electron {Mo(NO)}4 moiety. This di-iodide reacts with p-toluidine to give [Mo(NO)Ll(NHC6H4Me-p)] but is decomposed by alcohols or phenols. Reactions with the chelating ligands toluene-3,4-dithiol and 2-aminobenzenethiol afford [Mo(NO)L{SC6H3(Me)S}] and [Mo(NO)L(SC6H4NH)] respectively.

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Article information

DOI
https://doi.org/10.1039/DT9880002769
Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 2769-2773

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The syntheses and electrochemistry of some molybdenum mononitrosyl complexes containing the tripodal ligand [Co(η5-C5H5){P([double bond, length half m-dash]O)(OEt)2}3]–

S. S. Salam, C. J. Jones and J. A. McCleverty, J. Chem. Soc., Dalton Trans., 1988, 2769 DOI: 10.1039/DT9880002769

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