Darzens reaction between dialdosugar (1) and alkyl dihalogenoacetates afforded, in high yields, α-halogenoglycidic esters, which can be easily transformed into pyruvic derivatives.
P. Coutrot, C. Grison, M. Tabyaoui, S. Czernecki and J. Valery, J. Chem. Soc., Chem. Commun., 1988, 1515 DOI: 10.1039/C39880001515
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