Issue 22, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Palladium(II)/(III) complexes of triaza macrocycles: synthesis and single crystal X-ray structures of [PdIII(tacn)2]3+ and [PdII(tacn)(tacnH)]3+(tacn = 1,4,7-triazacyclononane)

Alexander J. Blake,   Linda M. Gordon,   Alan J. Holder,   Timothy I. Hyde,   Gillian Reid  and  Martin Schröder  

Abstract

The complex cation [Pd(tacn)2]2+(tacn = 1,4,7-triazacyclononane) shows a one-electron oxidation at E½=+0.07 V vs. Fc/Fc+(ferrocene/ferrocinium) to afford the stable mononuclear PdIII species [Pd(tacn)2]3+, which has a tetragonally-distorted octahedral structure with Pd–N(1)= 2.180(9), Pd–N(4)= 2.118(9), Pd–N(7)= 2.111(9)Å.

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Article information

DOI
https://doi.org/10.1039/C39880001452
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1452-1454

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Palladium(II)/(III) complexes of triaza macrocycles: synthesis and single crystal X-ray structures of [PdIII(tacn)2]3+ and [PdII(tacn)(tacnH)]3+(tacn = 1,4,7-triazacyclononane)

A. J. Blake, L. M. Gordon, A. J. Holder, T. I. Hyde, G. Reid and M. Schröder, J. Chem. Soc., Chem. Commun., 1988, 1452 DOI: 10.1039/C39880001452

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