Stereocontrolled synthesis of (±)-debromoaplysin and (±)-aplysin

Arun Ghosh; Sujay Biswas; Ramanathapuram V. Venkateswaran

doi:10.1039/C39880001421

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Stereocontrolled synthesis of (±)-debromoaplysin and (±)-aplysin

Arun Ghosh, Sujay Biswas and Ramanathapuram V. Venkateswaran

Abstract

A short and high yield synthesis of the marine sequiterpenoids Debromoaplysin (2) and Aplysin (1) is reported involving intramolecular ketene–alkene cycloaddition as a key step.

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DOI: https://doi.org/10.1039/C39880001421
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1988, 1421-1421

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Stereocontrolled synthesis of (±)-debromoaplysin and (±)-aplysin

A. Ghosh, S. Biswas and R. V. Venkateswaran, J. Chem. Soc., Chem. Commun., 1988, 1421 DOI: 10.1039/C39880001421

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Journal of the Chemical Society, Chemical Communications

Stereocontrolled synthesis of (±)-debromoaplysin and (±)-aplysin

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Stereocontrolled synthesis of (±)-debromoaplysin and (±)-aplysin

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