The rate of conversion of CH4 in the oxidative coupling reaction over a Li/MgO catalyst at 750 °C is 1.5 times greater than that of CD4 demonstrating that C–H bond breaking is the rate determining step in this reaction.
N. W. Cant, C. A. Lukey, P. F. Nelson and R. J. Tyler, J. Chem. Soc., Chem. Commun., 1988, 766 DOI: 10.1039/C39880000766
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