A highly stereospecific oxidation of 2-phospholene 1-oxides gives the first successful preparation of phospho sugars, having phosphorus as the sugar ring hetero atom, the relative configuration being confirmed by X-ray crystallography.
M. Yamashita, M. Uchimura, A. Iida, L. Parkanayi and J. Clardy, J. Chem. Soc., Chem. Commun., 1988, 569 DOI: 10.1039/C39880000569
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