Issue 1, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

The reaction of di-iodoacetylene with [Pd2Cl2(µ-Ph2PCH2PPh2)2]: formation of [Pd2Cl2(µ-σ-C[double bond, length half m-dash]CCl2)(µ-Ph2PCH2PPh2)2] and [Pdl2(Ph2PCH2PPh2)]

Julian A. Davies,   A. Alan Pinkerton,   Rashid Syed  and  Mark Vilmer  

Abstract

The complex [Pd2Cl2(µ-Ph2PCH2PPh2)2] reacts with di-iodoacetylene to yield [Pdl2(PPh2CH2PPh2)] and [Pd2Cl2(µ-σ-C[double bond, length half m-dash]CCl2)(µ-Ph2PCH2PPh2)2], which have been characterized by spectroscopic methods and by X-ray crystallography; formation of the bridged dichlorovinylidene complex involves a formal 1,2-halide shift accompanied by C–l/Pd–Cl bond metathesis.

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Article information

DOI
https://doi.org/10.1039/C39880000047
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 47-49

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The reaction of di-iodoacetylene with [Pd2Cl2(µ-Ph2PCH2PPh2)2]: formation of [Pd2Cl2(µ-σ-C[double bond, length half m-dash]CCl2)(µ-Ph2PCH2PPh2)2] and [Pdl2(Ph2PCH2PPh2)]

J. A. Davies, A. A. Pinkerton, R. Syed and M. Vilmer, J. Chem. Soc., Chem. Commun., 1988, 47 DOI: 10.1039/C39880000047

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