Issue 1, 1988

Formation of three-membered rings from γ-lodoketones and γ-lodoesters via 1,3-elimination

Abstract

γ-Iodoketones, prepared by ene–halogenocyclization of α-haloketones with Pd(PPh3)4, on treatment with diazabicyclo[5.4.0]undec-7-ene afford three-membered ring compounds in good yield via syn-1,3-elimination, presumably via W-shaped transition states.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 12-14

Formation of three-membered rings from γ-lodoketones and γ-lodoesters via 1,3-elimination

M. Mori, N. Kanda, Y. Ban and K. Aoe, J. Chem. Soc., Chem. Commun., 1988, 12 DOI: 10.1039/C39880000012

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