The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5)2(CO)4] and [ Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(µ-H)(CO)10(µ-OR)], previously inaccessible by thermal routes.
S. Aime, M. Botta, R. Gobetto, D. Osella and F. Padovan, J. Chem. Soc., Dalton Trans., 1987, 253 DOI: 10.1039/DT9870000253
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