Issue 23, 1987

The hydrogen bond as a key factor in efficient intramolecular proton transfer catalysis

Abstract

Efficient intramolecular catalysis by the Me2NH+ group of the naphthylammonium derivative (6) suggests that the thermodynamic stabilisation of the leaving group by intramolecular H-bonding plays a key kinetic role.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1774-1775

The hydrogen bond as a key factor in efficient intramolecular proton transfer catalysis

A. J. Kirby and J. M. Percy, J. Chem. Soc., Chem. Commun., 1987, 1774 DOI: 10.1039/C39870001774

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