Issue 21, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Rational synthesis of dinuclear complexes of platinum(I) and platinum(II) containing bridging ortho-metallated triphenylphosphine ligands from the monomeric bis(chelate) platinum(II) complex Pt(o-C6H4PPh2)2

Martin A. Bennett,   David E. Berry,   Suresh K. Bhargava,   Evert J. Ditzel,   Glen B. Robertson  and  Anthony C. Willis  

Abstract

Comproportionation of Pt(PPh3)3 and the bis(chelate) complex Pt(o-C6H4PPh2)2 gives a dinuclear complex Pt2(µ-o-C6H4PPh2)2(PPh 3)2 which is shown by X-ray crystallography to contain two ortho-metallated triphenylphosphine ligands bridging a PtI–PtI bond [Pt–Pt 2.630(1)Å]; addition of iodine gives a salt [Pt2(µ-l)(µ-o-C6H4PPh2)2(PPh3)2]l, the cation of which has an A-frame structure [Pt–Pt 2.931(2)Å].

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Article information

DOI
https://doi.org/10.1039/C39870001613
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1613-1615

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Rational synthesis of dinuclear complexes of platinum(I) and platinum(II) containing bridging ortho-metallated triphenylphosphine ligands from the monomeric bis(chelate) platinum(II) complex Pt(o-C6H4PPh2)2

M. A. Bennett, D. E. Berry, S. K. Bhargava, E. J. Ditzel, G. B. Robertson and A. C. Willis, J. Chem. Soc., Chem. Commun., 1987, 1613 DOI: 10.1039/C39870001613

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