The oxo complex [Mo(η5-C5H5)2(O)](2) reacts with PhNCO to form the structurally characterized cyclometallacarbamate [Mo(η5-C5H5)2{OC(O)N(Ph)}](3), derived from the formal [2 + 2] coupling of the C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
N double bond of an isocyanate with a terminal metal-oxo linkage.
P. Jernakoff, G. L. Geoffroy, A. L. Rheingold and S. J. Geib, J. Chem. Soc., Chem. Commun., 1987, 1610 DOI: 10.1039/C39870001610
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