An aqueous suspension of hydrous ferric oxide photocatalyses reduction of molecular nitrogen to ammonia with oxidation of water; the catalytic activity of this material is attributed to the strongly negative flat band potential and chemisorption of N2.
K. Tennakone, S. Wickramanayake, C. A. N. Fernando, O. A. Ileperuma and S. Punchihewa, J. Chem. Soc., Chem. Commun., 1987, 1078 DOI: 10.1039/C39870001078
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