Photolysis of the complex [Mo(σ-[graphic omitted])(CO)3(η-C5H5)] causes elimination of carbon monoxide and formation of [Mo(η2-[graphic omitted])(CO)2(η-C5H5)] in which the ring behaves as a di-hapto, formally three-electron donor.
E. W. Abel, S. R. Allen, P. A. Bates, M. B. Hursthouse and B. Khandelwal, J. Chem. Soc., Chem. Commun., 1987, 983 DOI: 10.1039/C39870000983
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