The first synthesis of 3-deoxy-D-glycero-D-galacto-nonulosonic acid (KDN)(1) was achieved by condensation of the non-nitrogeneous substrate D-mannose (2) with pyruvate, catalysed by immobilized acylneuraminate pyruvate lyase.
C. Augé and C. Gautheron, J. Chem. Soc., Chem. Commun., 1987, 859 DOI: 10.1039/C39870000859
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