A study of the angular variation of the e.s.r. signals obtained with an X-irradiated single crystal of Ph3As+CH3I–(g-tensor, 75As and 127I hyperfine tensors) showed that the radiogenic adduct Ph3As⋯ĊH3 gave rise to the arsoranyl radical Ph3AsI. The mechanism which leads from Ph3As+CH3 to Ph3AsI, via the successive formation of Ph3ÅsCH3 and Ph3As⋯ĊH3, is discussed.
M. Geoffroy, A. Llinares and S. P. Mishra, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 521 DOI: 10.1039/F19868200521
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