Iron(II) monocarbonyl complexes of the type [FeX(CO)L4]BPh4[X = Cl or Br; L = P(OMe)3′ P(OEt)3′ or PPh(OEt)2] and the dicarbonyl compound [FeBr(CO)2{PPh(OEt)2}3] BPh4 have been prepared and characterized by i.r.,1H and 31P-{1H} n.m.r. spectroscopy. Reactivity with some π-acceptor ligands has been investigated and synthesis of the new derivatives [FeBr(4-Me-C6H4NC)3L2]+[L = P(OMe)3′ P(OEt)3′ or PPh(OEt)2] achieved.
G. Albertin, D. Baldan and E. Bordignon, J. Chem. Soc., Dalton Trans., 1986, 329 DOI: 10.1039/DT9860000329
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