Issue 18, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Reactivity of a phosphavinylidene. Reactions at both phosphorus–carbon and phosphorus–molybdenum double bonds and a new approach to three-electron donor phosphide complexes

Atta M. Arif,   Alan H. Cowley  and  Sapé Quashie  

Abstract

The phosphavinylidene, [Mo(CO)2{η1-P[double bond, length as m-dash]C(SiMe3)2}(η-C5H5)], reacts with both electrophilic and nucleophilic reagents, thus representing a new synthetic method for 3e– donor phosphide complexes; MeOH will add to both the phosphorous–carbon and molybdenum–phosphorus double bonds.

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Article information

DOI
https://doi.org/10.1039/C39860001437
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1437-1438

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Reactivity of a phosphavinylidene. Reactions at both phosphorus–carbon and phosphorus–molybdenum double bonds and a new approach to three-electron donor phosphide complexes

A. M. Arif, A. H. Cowley and S. Quashie, J. Chem. Soc., Chem. Commun., 1986, 1437 DOI: 10.1039/C39860001437

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