Issue 17, 1986

Photoreduction of 5-deazaflavins [1,3,9-triaza-anthracene-2(3H),4(10H)-diones]

Abstract

Prolonged illumination of 8-X-5-deazaflavins (X = NH2 or NMe2) in the presence of triethanolamine as electron donor leads to the formation of 6,7-dihydro-8-X-5-deazaflavins, while using ethylenediaminetetra-acetate or oxalate as electron donor, besides the 6,7-dihydro compound the dimeric product 5,5′-bis(1,5-dihydro-3-carboxymethyl-8-X-5-deazaflavin) is formed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1385-1387

Photoreduction of 5-deazaflavins [1,3,9-triaza-anthracene-2(3H),4(10H)-diones]

P. A. J. Link, H. C. van der Plas and F. Müller, J. Chem. Soc., Chem. Commun., 1986, 1385 DOI: 10.1039/C39860001385

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