Issue 15, 1986

Regioselective hydroxylation in the B ring of ent-kaurene; syntheses of ent-7β- and 9α-hydroxykaur-16-enes

Abstract

Regioselective hydroxylation at the C-7 and the C-9 position of ent-kaur-16-ene (2) was achieved via radical cyclization of a hydroxymethyl group introduced at the C-15 position followed by removal of the carbon atom at C-15.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1164-1166

Regioselective hydroxylation in the B ring of ent-kaurene; syntheses of ent-7β- and 9α-hydroxykaur-16-enes

M. Node, T. Kajimoto, N. Ito, J. Tamada, E. Fujita and K. Fuji, J. Chem. Soc., Chem. Commun., 1986, 1164 DOI: 10.1039/C39860001164

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