The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex [TMP = the dianion of 5, 10, 15,20-tetramesitylporphyrin].
M. J. Camenzind, B. R. James and D. Dolphin, J. Chem. Soc., Chem. Commun., 1986, 1137 DOI: 10.1039/C39860001137
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