The Iron(III) complex of the porphyrin meso-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)prophyrin, (1-H2), reacts with certain thiols in basic dimethyl sulphoxide solution at 25 °C to give products having hyperporphyrin spectra similar to those of thiolate complexes of iron(III)–cytochrome P-450.
K. B. Nolan, J. Chem. Soc., Chem. Commun., 1986, 760 DOI: 10.1039/C39860000760
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