Benzylic, aryl, and alkyl halides react with formate esters and carbon monoxide, in the presence of the dimer of chloro(hexa-1,5-diene)rhodium(I), [1,5-HDRhCl]2, to give carboxylic esters; bimetallic catalysis {i.e., Pd(PPh3)4/[1,5-HDRhCl]2} is particularly beneficial when an aromatic halide is used as the substrate.
C. Buchan, N. Hamel, J. B. Woell and H. Alper, J. Chem. Soc., Chem. Commun., 1986, 167 DOI: 10.1039/C39860000167
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