The presence of a peroxocarbonate species, likely to be HCO4– in pH-dependent equilibrium with CO42–, in solutions of HCO3– in an excess of H2O2 is inferred from Raman and 13C n.m.r. spectroscopy; similar evidence is presented for the presence of CO42– in solutions prepared by dissolving solid peroxocarbonates (NaHCO4·H2O and K2C2O6) in aqueous alkali.
J. Flangan, D. P. Jones, W. P. Griffith, A. C. Skapski and A. P. West, J. Chem. Soc., Chem. Commun., 1986, 20 DOI: 10.1039/C39860000020
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