The bromovinyl radical has been prepared by the reaction of bromine atoms with acetylene in an argon matrix at 17 K and its i.r. spectrum has been studied. The spectrum of C2H DBr˙ shows the presence of two isomers, indicating that the radical has an unsymmetric structure.
A. Engdahl and B. Nelander, J. Chem. Soc., Perkin Trans. 2, 1985, 1747 DOI: 10.1039/P29850001747
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