Issue 0, 1985

Neighbouring group participation in the allylic oxidation of a Δ5-steroid

Abstract

When 3β-acetoxy-Δ5-steroids are treated with bromine and silver acetate, the product 3β-hydroxy-4β-acetate is formed by intramolecular acetoxy group migration via a 3β,4β-acetoxylinium ion

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 647-649

Neighbouring group participation in the allylic oxidation of a Δ5-steroid

J. R. Hanson and P. B. Reese, J. Chem. Soc., Perkin Trans. 1, 1985, 647 DOI: 10.1039/P19850000647

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