Issue 22, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

The very high activity of (Ph2P)2C[double bond, length half m-dash]CH2 to Michael additions when complexed to platinum(II) or platinum(IV)

Xavier L. R. Fonmtaine,   Fatma S. M. Hassan,   Simon J. Higgins,   Grant B. Jacobsen,   Bernard L. Shaw  and  Mark Thornton-Pett  

Abstract

Complexes of the types [PtMe2(vdpp)], [PtMe3l(vdpp)], or [PtX2(vdpp)]{X = Cl or I, vdpp =(Ph2P)2C[double bond, length half m-dash]CH2} undergo Michael additions with various amines, hydrazines, or carbon nucleophiles (ethyl acetoacetate or acetone) to the vinylidene double bond; [PtMe3I(Ph2P)2CHCH2NHCH2Ph] isomerizes to [PtMe3I{Ph2P2PCH(PPh2)CHNCH2Ph}].

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Article information

DOI
https://doi.org/10.1039/C39850001635
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1635-1636

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The very high activity of (Ph2P)2C[double bond, length half m-dash]CH2 to Michael additions when complexed to platinum(II) or platinum(IV)

X. L. R. Fonmtaine, F. S. M. Hassan, S. J. Higgins, G. B. Jacobsen, B. L. Shaw and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1985, 1635 DOI: 10.1039/C39850001635

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