Issue 16, 1985

An exceptionally mild, catalytic homogeneous method for the conversion of amines into carbamate esters

Abstract

Aromatic amines react at room temperature and atmospheric pressure with carbon monoxide, oxygen, alcohols, and hydrochloric acid, with palladium chloride as the catalyst and copper(II) chloride as re-oxidant to give carbamate esters in fair to quantitative yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1141-1142

An exceptionally mild, catalytic homogeneous method for the conversion of amines into carbamate esters

H. Alper and F. W. Hartstock, J. Chem. Soc., Chem. Commun., 1985, 1141 DOI: 10.1039/C39850001141

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