The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy of 6.4 kcal mol–1(26.8 kJ mol–1) was obtained for the 1,2-H migration in benzylchlorocarbene.
M. T. H. Liu, J. Chem. Soc., Chem. Commun., 1985, 982 DOI: 10.1039/C39850000982
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