Issue 9, 1985

Diplatinum(0) complexes [Pt2(µ-R2PCH2PR2)3(PPh3)n], n= 0–2: the molecular structure of the complex with R = Me, n= 1

Abstract

Two new structural type of binuclear platinum(0) complexes of formula [Pt2(µ-R2PCH2PR2)3(PPh3)], (2), and [Pt2(µ-R2PCH2PR2)3(PPh3)2], (3), have been characterized by n.m.r. spectroscopy and, for (2; R = Me), by X-ray crystallography; steric requirements of R determine the preferred structure and complexes (2; R = Me or Et) are shown to contain both 3-co-ordinate and 4-co-ordinate platinum(0) centres.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 566-567

Diplatinum(0) complexes [Pt2(µ-R2PCH2PR2)3(PPh3)n], n= 0–2: the molecular structure of the complex with R = Me, n= 1

S. S. M. Ling, I. R. Jobe, A. J. McLennan, L. Manojlović-Muir, K. W. Muir and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1985, 566 DOI: 10.1039/C39850000566

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