Syntheses are described for pure paraffins having 102, 150,198, 246, and 390 carbon atoms; unlike lower homologues, all but the first show interesting properties in the solid state, bridging the gap between the chain-extended and the chain-folded modes of crystallisation typical of the lower n-paraffins and the linear polyethylenes, respectively.
I. Bidd and M. C. Whiting, J. Chem. Soc., Chem. Commun., 1985, 543 DOI: 10.1039/C39850000543
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