Issue 7, 1985

The oxidation of organic compounds with iodosylbenzene catalysed by tetra(4-N-methylpyridyl)porphyrinatoiron(III) pentacation: a polar model system for the cytochrome P450 dependent mono-oxygenases

Abstract

Replacing the tetraphenylporphyrinatoiron(III) chloride (FeIIITPPCl) catalyst, in Groves' model system (FeIIITPPCl–PhIO) for cytochrome P450 mono-oxygenases, with tetra(4-N-methylpyridyl)porphyrinatoiron(III) pentacation allows oxidations to be carried out in protic and dipolar solvents aprotic solvents without significantly altering the mechanisms of the reactions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 410-411

The oxidation of organic compounds with iodosylbenzene catalysed by tetra(4-N-methylpyridyl)porphyrinatoiron(III) pentacation: a polar model system for the cytochrome P450 dependent mono-oxygenases

J. R. L. Smith and D. N. Mortimer, J. Chem. Soc., Chem. Commun., 1985, 410 DOI: 10.1039/C39850000410

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