(Trimethylsily)trimethylstannane adds regio- and stereo-specifically to alk-1-ynes in the presence of tetrakis(triphenylphosphine)palladium(0); regiospecific addition to 1,1-dimethylallene is also observed.
T. N. Mitchell, H. Killing, R. Dicke and R. Wickenkamp, J. Chem. Soc., Chem. Commun., 1985, 354 DOI: 10.1039/C39850000354
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